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Modern conversion refineries may produce two-thirds of their output as unleaded gasoline, with the balance distributed between liquefied petroleum gas, jet fuel, diesel fuel, and a small quantity of coke Many such refineries also incorporate solvent extraction processes for manufacturing lubricants and petrochemical units with which to recover propylene, benzene, toluene, and xylene for further processing into polymers Finally, the yields and quality of refined petroleum products produced by any given oil refinery depends on the mixture of crude oil used as feedstock and the configuration of the refinery facilities Light/sweet crude oil is generally more expensive and has inherent great yields of higher value low-boiling products such as naphtha, gasoline, jet fuel, kerosene, and diesel fuel Heavy sour crude oil is generally less expensive and produces greater yields of lower value high-boiling products that must be converted into low-boiling products.

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This chapter presents an overview of petroleum refining in order for the reader to place each process in the correct context of fuels production..

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Part 2:

Notice the XML is properly formed; however, there s a mistake in the customer type attribute. The DTD provides the allowable values of retail or wholesale. If the attribute isn t present in the XML, the customer type attribute defaults to retail, according to the DTD. The XML has a value of manufacturing. This produces a warning in the XML document, but it doesn t prevent the XML from being parsed because it s still properly formed XML. Try changing the customer tag to:

Downloaded from Digital Engineering Library @ McGraw-Hill (www.digitalengineeringlibrary.com) Copyright 2004 The McGraw-Hill Companies. All rights reserved. Any use is subject to the Terms of Use as given at the website.

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An acid base titration is a laboratory procedure commonly used to determine the concentration of an unknown solution A base solution of known concentration is added to an acid solution of unknown concentration (or vice versa) until an acid base indicator visually signals that the end point of the titration has been reached The equivalence point is the point at which a stoichiometric amount of the base has been added to the acid Both chemists and chemistry students hope that the equivalence point and the end point are close together If the acid being titrated is a weak acid, then there are equilibria which will be established and accounted for in the calculations.

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Typically, a plot of pH of the weak acid solution being titrated versus the volume of the strong base added (the titrant) starts at a low pH and gradually rises until close to the equivalence point, where the curve rises dramatically After the equivalence point region, the curve returns to a gradual increase This is shown in Figure 153 In many cases, one may know the initial concentration of the weak acid, but may be interested in the pH changes during the titration To study the changes one can divide the titration curve into four distinctive areas in which the pH is calculated 1 Calculating the initial pH of the weak acid solution is accomplished by treating it as a simple weak acid solution of known concentration and Ka 2 As base is added, a mixture of weak acid and conjugate base is formed.

This is a buffer solution and can be treated as one in the calculations Determine the moles of acid consumed from the moles of titrant added that will be the moles of conjugate base formed Then calculate the molar concentration of weak acid and conjugate base, taking into consideration the volume of titrant added Finally, apply your buffer equations 3 At the equivalence point, all the weak acid has been converted to its conjugate base The conjugate base will react with water, so treat it as a weak base solution and calculate the [OH ] using Kb Finally, calculate the pH of the solution 4 After the equivalence point, you have primarily the excess strong base that will determine the pH..

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